Formation of cyclopentenone upon photo-oxidation of the cyclopropyl (c-C3H5) carbyne complex [(η5-C5H5){P(OMe)3}(CO)WC(c-C3H5)]
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 624-625
- https://doi.org/10.1039/c39900000624
Abstract
Photo-oxidation of the carbyne complex [(η5-C5H5){P(OMe)3}(CO)WC(c-C3H5)] by irradiation in CHCl3 results in formation of [(η5-C5H5){P(OMe)3}(CO)WCl3] and partial recovery of the lost cyclopropyl carbyne ligand as cyclopentenone.Keywords
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