Generation and fate of 1-adamantyl-vinyl cations
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 22,p. 1349-1350
- https://doi.org/10.1039/c29690001349
Abstract
The 1-(1-adamantyl)vinyl cations (II), generated in sulphuric acid either by addition of 1-adamantyl carbonium ions to acetylene or by protonation of 1-adamantylacetylenes (I), are transformed into mixtures of 1-adamantyl methyl ketones (III) and homoadamantan-4-ones (V).Keywords
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