New methods for metal–carbon bond formation; reactions of (OC)5MnSiMe3with cyclic ethers
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1260-1261
- https://doi.org/10.1039/c39800001260
Abstract
When (OC)5MnSiMe3(1) is treated with cyclic ethers (ring size ⩽ 5), ring opening and metal–carbon bond formation occurs; under 200 lb in–2 of CO, high yields of products (OC)5Mn(COR) can be obtained.Keywords
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