THE ACTIVATION PROCESS IN SOLVOLYSIS
- 1 July 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (7) , 1707-1711
- https://doi.org/10.1139/v64-254
Abstract
The structural nature of water is a major factor in determining the solvent isotope effect and the apparent heat capacity of activation for solvolysis. The consequences of this assumption are examined for the SN2 mechanism in terms of solvation changes at the transition state and the probable make-up of the activation energy.Keywords
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