Palladium-Catalyzed Synthesis of Aqueous, Fluorous, and Supercritical CO2-Soluble Phosphines
- 22 July 2000
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (17) , 2675-2677
- https://doi.org/10.1021/ol006203+
Abstract
A generic, simple, and economical route has been developed for the synthesis of phosphines soluble in aqueous, fluorous, and supercritical CO2 phases. The methodology is based on the palladium-catalyzed Heck olefination of haloarylphosphine oxides followed by reduction, affording various arylphosphines in high yields.Keywords
This publication has 17 references indexed in Scilit:
- Effect of Ligand Modification on Rhodium-Catalyzed Homogeneous Hydroformylation in Supercritical Carbon DioxideOrganometallics, 1999
- The rhodium catalysed hydrogenation of styrene in the fluorous biphaseJournal of Fluorine Chemistry, 1999
- Room-Temperature Ionic Liquids. Solvents for Synthesis and CatalysisChemical Reviews, 1999
- Fluorous phase separation techniques in catalysisChemical Society Reviews, 1999
- Rhodium-Catalyzed Hydroformylation in Supercritical Carbon DioxideJournal of the American Chemical Society, 1998
- Design and Development of Functionalized Water-Soluble Phosphines: Catalytic and Biomedical ImplicationsAccounts of Chemical Research, 1998
- Fluorous Biphase ChemistryAccounts of Chemical Research, 1998
- The Preparation, Characterization, and Properties of Highly Soluble Transition-Metal Complexes of Long-Chain Tertiary PhosphinesPublished by American Chemical Society (ACS) ,1982
- Preparation and properties of tertiary p-alkylarylphosphines containing straight-chain alkyl groupsJournal of the Chemical Society, Perkin Transactions 1, 1980
- 1H nuclear magnetic resonance study of para-substituted derivatives of triphenylphosphineJournal of the Chemical Society, Perkin Transactions 2, 1974