Studies of ion molecule reactions using a multiple quadrupole mass spectrometer. Part 3. The reactions of alkenyl radical cations C n H2n + with alkenes
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 8,p. 1197-1203
- https://doi.org/10.1039/p29860001197
Abstract
The gas-phase reactions of ethenyl (C2H4 +˙), propenyl (C3H6 +˙), and butenyl (C4H8 +˙) with each of ethene, propene, but-1-ene, cis-but-2-ene, and 2-methylpropene have been reinvestigated using a triple quadrupole mass spectrometer. The present results are on the whole in good agreement with earlier studies, but the triple quadrupole enables reactions to be studied over a wider pressure range than the majority of previous investigations. It is particularly easy to isolate proposed sequences and thus to confirm (or disprove) particular reaction pathways.Keywords
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