Diffusion, adsorption and desorption at surfaces
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 86 (8) , 1299-1305
- https://doi.org/10.1039/ft9908601299
Abstract
To understand mass transport at surfaces, a macroscopic theory is advanced based on the Onsager approach to non-equilibrium thermodynamics. A microscopic basis is then sought by re-examining the kinetic lattice-gas model to generalize the underlying dynamics for adsorption, desorption and diffusion.Keywords
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