Computing counterion densities at intermediate coupling
- 25 April 2006
- journal article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 73 (4) , 041512
- https://doi.org/10.1103/physreve.73.041512
Abstract
By decomposing the Coulomb interaction into a long-distance component appropriate for mean-field theory, and a non-mean-field short distance component, we compute the counterion density near a charged surface for all values of the counterion coupling parameter. A modified strong-coupling expansion that is manifestly finite at all coupling strengths is used to treat the short-distance component. We find a nonperturbative correction related to the lateral counterion correlations that modifies the density at intermediate coupling.Keywords
All Related Versions
This publication has 33 references indexed in Scilit:
- Electrostatic correlations: from plasma to biologyReports on Progress in Physics, 2002
- Colloquium: The physics of charge inversion in chemical and biological systemsReviews of Modern Physics, 2002
- Macroions in Salty Water with Multivalent Ions: Giant Inversion of ChargePhysical Review Letters, 2000
- Screening of a charged particle by multivalent counterions in salty water: Strong charge inversionThe Journal of Chemical Physics, 2000
- Screening of a macroion by multivalent ions: a new boundary condition for the Poisson–Boltzmann equation and charge inversionPhysica A: Statistical Mechanics and its Applications, 1999
- Screening of a macroion by multivalent ions: Correlation-induced inversion of chargePhysical Review E, 1999
- Charge inversion in electric double layers and effects of different sizes for counterions and coionsThe Journal of Chemical Physics, 1998
- Double layer interactions in mono- and divalent electrolytes: A comparison of the anisotropic HNC theory and Monte Carlo simulationsThe Journal of Chemical Physics, 1992
- Correlation and image charge effects in electrical double layersChemical Physics Letters, 1985
- Correlation and image charge effects in electric double layersChemical Physics Letters, 1984