endo-H and exo-H-(cyclopentadienyl)(pentamethylcyclopentadiene)rhodium(I) and the relative reactivities of endo- and exo-substituents
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 616b-617
- https://doi.org/10.1039/c2969000616b
Abstract
In the two isomers of C5H5RhC5Me5H, the exo-substituent is more reactive than the endo-substituent. The endo-H is postulated to react via an intramolecular transfer to the other ring.Keywords
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