Magnetic Transition of Wurster's Blue Perchlorate. I. The Low-Temperature Phase
- 15 July 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (2) , 395-401
- https://doi.org/10.1063/1.1711907
Abstract
Evidence is given for the low‐temperature phase of Wurster's blue perchlorate being built up of bipositive ions and neutral molecules, the high‐temperature phase having undergone disproportionation according to 2 TMPD+→TMPD+TMPD++. The electronic as well as the ESR spectra can be explained on this basis. The actual transfer of charge required in the disporportionation can be observed as a conductivity peak in the transition range.Keywords
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