Free radical addition to olefins. Part 2.—Addition of trichloromethyl radicals to fluoroethylenes
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 1859-1865
- https://doi.org/10.1039/tf9666201859
Abstract
Arrhenius parameters have been determined for the addition of trichloromethyl radicals to fluoroethylenes; for the unsymmetric olefins the parameters have been determined for each end of the double bond. [graphic omitted] The determined activation energies are compared with localization energies, and with free valence as calculated from simple Hückel theory.Keywords
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