Metal Isotope Effect on Raman Spectrum of [Zn(NH3)4]I2 Crystals

Abstract
The Raman spectra of [64Zn(NH3)4]I2 and its 68Zn analog have been measured in the crystalline state. The Zn–N stretching vibrations have been assigned based on the observed metal isotope shifts. These shifts have been compared with theoretical values obtained from a complete normal coordinate analysis on the [Zn(NH3)4]2+ ion.

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