Raman and infrared study of KHSO4 crystal
- 1 October 1980
- journal article
- Published by Wiley in Journal of Raman Spectroscopy
- Vol. 9 (5) , 297-303
- https://doi.org/10.1002/jrs.1250090505
Abstract
The Raman spectra of the low temperature phase single crystal of KHSO4 and of polycrystalline KDSO4 have been investigated at 300 and 90 K. Infrared spectra of polycrystalline samples have been recorded for compaison in the 4000 to 30 cm−1 range. An assignment of bands due to internal vibrations to their symmetry species (Raman) and in terms of approximate type of motion is given. a distinction between the bands corresponding to cyclic dimers and infinite chains is possible in the case of the OH group and most skeletal stretching vibrations. An interpretation of lattice bands using an oriented gas model is proposed. Hydrogen bonding in the KHSO4 crystal is discussed.Keywords
This publication has 14 references indexed in Scilit:
- Hydrogen bonding in solids correlation of spectroscopic and crystallographic dataPublished by Springer Nature ,2007
- On the hydrogen bonding in potassium hydrogensulphate. Comparison with a previous crystal structure determinationActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1976
- Spectres de vibration des acides H2SO4 et D2SO4 à l'état cristalliséSpectrochimica Acta Part A: Molecular Spectroscopy, 1975
- Low temperature Raman spectra of NH3SO3 and ND3SO3 single crystalsJournal of Raman Spectroscopy, 1975
- The structure of potassium hydrogen sulfateActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1975
- Low temperature Raman spectra of KHCO3 single crystalJournal of Raman Spectroscopy, 1973
- Normal coordinate analysis of the monobasic sulphate ionJournal of Molecular Structure, 1973
- Refinements of structures containing bonds between Si, P, S or Cl and O or N. VIII. KHSO4(mercallite)Acta Crystallographica, 1964
- The crystal structure of KHSO4(mercallite)Acta Crystallographica, 1958
- Melting and crystal structure. III.—low-melting acid sulphatesTransactions of the Faraday Society, 1950