A thermodynamic model of the mixed-salt cobalt(II)–hexacyanoferrate(II) ion exchanger
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 80 (4) , 823-829
- https://doi.org/10.1039/f19848000823
Abstract
A thermodynamic model for the ion exchange of K, NH4 and Cs on the ion exchanger cobalt(II)–hexacyanoferrate(II)–M where M = K,NH4 and Cs, has been postulated. Based on the experimentally determined thermodynamic functions ΔG⊖ exp, ΔS⊖ exp and ΔH⊖ exp and on the calculated values of excess functions, the deviations from ideality of the investigated reactions have been explained.Keywords
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