Geometries of transition metal complexes containing simple alkenes

Abstract
The results of precise X-ray studies of the fumaronitrile complex of hydridocarbonylbis(triphenylphosphine)iridium and of the tetracyanoethylene complex of bromocarbonylbis(triphenylphosphine) iridium are presented and detailed comparisons are made with the results on other simple olefin-metal structures available in the literature.

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