Raman Spectra of Thionyl Fluoride and Sulfuryl Fluoride
- 1 July 1955
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (7) , 1316-1317
- https://doi.org/10.1063/1.1742267
Abstract
The Raman spectra of liquid and gaseous sulfuryl fluoride (SO2F2) and of liquid thionyl fluoride (SOF2) have been investigated and depolization factors measured for the stronger lines scattered by the liquids. For SO2F2 the Raman shift due to the infrared inactive torsional mode has been found to be 388 cm—1, and other previous assignments based on the infrared spectrum have been confirmed. For SOF2, the symmetric SF2 stretch occurs at a higher frequency than the asymmetric stretch; the reverse is true for SO2F2. The symmetric SF2 bending mode has escaped detection for both compounds.Keywords
This publication has 5 references indexed in Scilit:
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- The Microwave Spectrum, Structure, and Dipole Moment of Thionyl Fluoride1Journal of the American Chemical Society, 1954
- The Infrared Spectrum of SO2F2The Journal of Chemical Physics, 1952
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- The Raman spectra of volatile fluorides. Applications of Raman spectra to chemical problemsProceedings of the Indian Academy of Sciences - Section A, 1938