Metal–sulphinate complexes. Part I. Benzenesulphinatopalladium(II) complexes
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1246-1248
- https://doi.org/10.1039/j19660001246
Abstract
The benzenesulphinate anion forms complexes with palladium(II) of the types [Pd(PhSO2)2(H2O)2], [PdX(PhSO2)2(H2O)]–, [PdX2(PhSO2)2]2–, [Pd(PhSO2)2L2], and [PdX(PhSO2)L2](X = anionic ligand, L = uncharged ligand). The ease of formation and the stability of the palladium–aquo-species indicates that the benzenesulphinato-ligand has a high trans-effect.Keywords
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