Synthesis and Characterization of Di-[3-(Trimethylsilyl)-1-Propylene] Alkylenediphosphonic Acids
- 1 January 2000
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 30 (12) , 2121-2132
- https://doi.org/10.1080/00397910008087391
Abstract
A homologous series of alkylenediphosphonic acids was successfully esterified with 3-(trimethylsilyl)-1-propanol to the symmetrically-substituted diesters. The procedure, which has general applicability for incorporating silicon heteroatoms into diphosphonic acids, utilizes the esterification reagent dicyclohexyl-carbodiimide (DCC) to activate the acid. The aggregation properties of the di-[3-(trimethylsilyl)-1-propylene] alkylenediphosphonic acids were measured in toluene and 1-decanol.Keywords
This publication has 14 references indexed in Scilit:
- High Yield Synthesis of Tetraethyl Alkylene-Diphosphonates via the Michaelis-Arbuzov ReactionSynthetic Communications, 1998
- An investigation of P, P′-di(2-ethylhexyl) methanediphosphonic acid and some of its metal complexesPolyhedron, 1997
- Diphonix® Resin: A Review of Its Properties and ApplicationsSeparation Science and Technology, 1997
- ACIDS. PART 1. P,P"-DI(2-ETHYLHEXYL) METHANEDIPHOSPHONIC ACIDSolvent Extraction and Ion Exchange, 1996
- Calorimetric and Laser Induced Fluorescence Investigation of the Complexation Geometry of Selected Europium-gem-Diphosphonate Complexes in Acidic SolutionsInorganic Chemistry, 1995
- Decontamination of Waste Solution from Davies-Gray Analyses in a Pilot-Facility for Process DevelopmentSeparation Science and Technology, 1995
- Actinide phosphonate complexes in aqueous solutionsJournal of Alloys and Compounds, 1994
- Siloxane Polymers and CopolymersPublished by Wiley ,1989
- Monoesters and Ester-amidates of Aromatic Phosphonic AcidsJournal of the American Chemical Society, 1957
- 465. Studies on phosphorylation. Part XI. The reaction between carbodi-imides and acid esters of phosphoric acid. A new method for the preparation of pyrophosphatesJournal of the Chemical Society, 1953