Derivatives of optically active 1-chloro-2,2-bismethoxycarbonylaziridine: absolute configuration and X-ray molecular structure of (–)-(E)-1-chloro-2-methoxycarbonyl-2-methylcarbamoylaziridine
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 538-539
- https://doi.org/10.1039/c39910000538
Abstract
X-Ray analysis of (–)-(E)-1-chloro-2-methoxycarbonyl-2-methylcarbamoylaziridine shows that the absolute configuration at the chiral centres is (–)-(1R,2R); this enables us to assign the S configuration to the chiral nitrogen atom in the related compound (+)-1-chloro-2,2-bismethoxycarbonylaziridine.Keywords
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