Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence {Fe(i)–Fe(ii)} bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase
- 5 March 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 700-701
- https://doi.org/10.1039/b111613b
Abstract
Iron(I) in biology?: one-electron oxidation of an {Fe(I)–Fe(I)} carbonyl cyanide precursor bearing a proximal thioether group leads to an {Fe(I)–Fe(II)} bridging carbonyl transient with spectral features similar to the di-iron sub-site of the CO inhibited paramagnetic centre of all-iron hydrogenase.Keywords
This publication has 0 references indexed in Scilit: