Charge carrier mobility in doped semiconducting polymers

Abstract
An analytic model of the equilibrium hopping conductivity in a disordered organic semiconductor at large charge carrier densities is formulated. Calculated dependences of the equilibrium hopping mobility upon the carrier density are compared with recent experimental data obtained on doped poly(3-hexylthiophene) films. Doping is shown to create additional energy disorder due to potential fluctuations caused by the Coulomb field of randomly distributed dopant ions.