Growth of epitaxial CaSi2 films on Si(111)
- 1 May 1988
- journal article
- Published by American Vacuum Society in Journal of Vacuum Science & Technology A
- Vol. 6 (3) , 1340-1342
- https://doi.org/10.1116/1.575697
Abstract
The growth of single-crystal epitaxial CaSi2 films on Si(111) is described along with a determination of the silicide atomic structure. Films were prepared using standard ultrahigh vacuum evaporation techniques in a silicon molecular beam epitaxy system. Cross-sectional transmission electron micrographs of atomically abrupt step-free interfaces extending well over 500 Å are presented. These films constitute the first example of an epitaxial non-transition-metal silicide. The lack of d electrons and the large difference in electronegativity between Ca and Si provide a new single-crystal metal/silicon interface with significantly different characteristics from the thoroughly studied transition-metal silicides.This publication has 0 references indexed in Scilit: