The interaction of chloranil with aliphatic amines
- 1 January 1964
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 83 (7) , 711-717
- https://doi.org/10.1002/recl.19640830711
Abstract
Although substitution of chlorine usually occurs in the interaction of chloranil with aliphatic amines, solutions of chloranil in pure triethylamine yield a product which appears to be a salt, the anion of which is the free radical semiquinone ion derived from chloranil. In acetone solution this salt decomposes to yield 2,3,5‐trichloro‐6‐(2′‐diethylaminovinyl)‐p‐benzoquinone.Keywords
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