Treatment of light atoms in X-ray structural studies on metal carbonyl clusters: a critical view
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 144-146
- https://doi.org/10.1039/c39870000144
Abstract
A significant ‘sliding’ of the C atoms towards the O atoms is observed on passing from isotropic to anisotropic refinement of the light atoms in conventional room temperature X-ray investigations on metal carbonyl clusters; differences in bond lengths are discussed with respect to results of neutron diffraction studies.Keywords
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