INTENSITY IN THE RAMAN EFFECT: III. THE EFFECT OF DEUTERIUM SUBSTITUTION ON THE INTENSITY OF RAMAN BANDS OF BENZENE
- 1 June 1955
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 33 (6) , 1137-1144
- https://doi.org/10.1139/v55-133
Abstract
Standard intensities of the Raman bands of C6H6, 1,3,5,-C6H3D3, and C6D6 have been obtained photoelectrically. An ambiguity in the vibrational assignment for 1,3,5,-C6D3H3 has been removed, and the assumption of the invariance of the polarizability and anisotropy derivatives upon isotopic substitution has been tested. A sum rule for depolarization ratios of Raman bands in isotopic homologues has been derived subject to the same assumptions used for obtaining the intensity sum rules.Keywords
This publication has 2 references indexed in Scilit:
- Photoelectric Raman SpectrometerJournal of the Optical Society of America, 1955
- Empirical Convergence Correction of Depolarization Measurements*Journal of the Optical Society of America, 1950