The structure of the decamethylborocenium cation: the most tightly-squeezed metallocene?
- 10 May 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 911-912
- https://doi.org/10.1039/b001271h
Abstract
X-Ray crystallographic analysis along with DFT calculations on the decamethylborocenium cation provide definitive structural and electronic information about this most tightly-squeezed main group metallocene—the first to adopt the elusive σ/π geometry in the solid state.Keywords
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