Ambident electrophilic character of thioxophosphoranesulphenyl bromides =P(S)SBr. A novel observation of electrophilic addition to a Carbon–Carbon double bond
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1362-1364
- https://doi.org/10.1039/c39820001362
Abstract
The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products –SC(R1)(R2)CR3(R4)(Br) or 1,2-dibromides and -disulphides.Keywords
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