Unseeded synthesis of Al-free Ti-β zeolite in fluoride medium: a hydrophobic selective oxidation catalyst
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2367-2368
- https://doi.org/10.1039/cc9960002367
Abstract
Al-free Ti-β zeolite spontaneously nucleates and grows in a reaction mixture containing tetraethylammonium and fluoride ions at near neutral pH, and shows an enhanced crystallinity and thermal and hydrothermal stability as well as a significant hydrophobic character.Keywords
This publication has 9 references indexed in Scilit:
- Solvent Effects during the Oxidation of Olefins and Alcohols with Hydrogen Peroxide on Ti-Beta Catalyst: The Influence of the Hydrophilicity–Hydrophobicity of the ZeoliteJournal of Catalysis, 1996
- Synthesis and catalytic activity of aluminium-free zeolite Ti-β oxidation catalystsChemical Communications, 1996
- Oxidation of Olefins with Hydrogen Peroxide and tert-Butyl Hydroperoxide on Ti-Beta CatalystJournal of Catalysis, 1995
- X-ray absorption spectroscopy of Ti-containing molecular sieves ETS-10, aluminum-free Ti-β, and TS-1Catalysis Letters, 1995
- Activity of Ti-Beta Catalyst for the Selective Oxidation of Alkenes and AlkanesJournal of Catalysis, 1994
- Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbonsJournal of the Chemical Society, Chemical Communications, 1994
- The state of Ti in titanoaluminosilicates isomorphous with zeolite .beta.Journal of the American Chemical Society, 1993
- Synthesis of a titaniumsilicoaluminate isomorphous to zeolite beta and its application as a catalyst for the selective oxidation of large organic moleculesJournal of the Chemical Society, Chemical Communications, 1992
- Spectroscopic Characterization of Silicalite and Titanium-SilicalitePublished by Elsevier ,1989