Flash Pyrolysis and Kinetic Spectroscopy of Ammonium Perchlorate
- 15 August 1967
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (4) , 1488-1490
- https://doi.org/10.1063/1.1712106
Abstract
The flash pyrolysis of ammonium perchlorate has been studied by kinetic spectroscopy. The absorption spectra of OH, ClO2, ClO, NO, and NH are described, and the relative concentration of each is given for the period of 1000 μsec following the initial photoflash. A mechanism for the flash pyrolytic decomposition of ammonium perchlorate is given in terms of the spectra observed. The flash pyrolytic data support the evidence that the initial step in the decomposition of ammonium perchlorate leads to the formation of ammonia and anhydrous perchloric acid. Subsequent reactions consist of the high‐temperature oxidation of ammonia by perchloric acid.Keywords
This publication has 15 references indexed in Scilit:
- Combination Flash Photolysis-Flash Pyrolysis SystemReview of Scientific Instruments, 1966
- Mass spectrometric study of the thermal decomposition of ammonium perchlorateTransactions of the Faraday Society, 1964
- Kinetic Absorption Spectra Recorded Edgewise Across Flash-Heated StripsApplied Optics, 1962
- Absorption Spectra of Gaseous Species Formed at Flash-Heated Solid SurfacesThe Journal of Chemical Physics, 1962
- Vacuum Ultra-Violet Absorption Spectra of Flash-heated Lead reacting with Various GasesNature, 1962
- Intense Rapid Heating with Flash Discharge LampsScience, 1962
- The thermal decomposition of ammonium perchlorate at low temperaturesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1960
- The thermal decomposition of ammonium perchlorate, II. The kinetics of the decomposition, the effect of particle size, and discussion of resultsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1955
- The thermal decomposition of ammonium perchlorate - І. Introduction, experimental, analysis of gaseous products, and thermal decomposition experimentsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1954
- Chemical Reactions Produced by Very High Light IntensitiesNature, 1949