17O Nuclear Magnetic Resonance of Single Crystals of D2O Ice
- 15 December 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (12) , 5338-5342
- https://doi.org/10.1063/1.1701799
Abstract
17O NMR spectra have been obtained for two orientations of a single crystal of D2O enriched to 22% in 17O. The spectra of only one orientation could be assigned. This assignment yields quadrupole coupling constants for 17O in ice as follows: | e2Qqzz/h | = 1.79±0.05 MHz, η=−1.01±0.04, where the z axis is the C2 axis of the D2O molecule The isotropic chemical shift is 612±37 ppm paramagnetic to liquid D2O.Keywords
This publication has 9 references indexed in Scilit:
- Oxygen-17 relaxation in waterThe Journal of Physical Chemistry, 1967
- Deuteron Magnetic Resonance of Polycrystalline DeuteroammoniaThe Journal of Chemical Physics, 1966
- Oxygen−17 NMR in Polycrystalline H2O and D2O IceThe Journal of Chemical Physics, 1966
- Deuteron Quadrupole Coupling in D2OThe Journal of Chemical Physics, 1966
- Nitric Oxide Distillation Plant for Isotope SeparationIndustrial & Engineering Chemistry Process Design and Development, 1965
- Nuclear Magnetic Resonance of Single Crystals of D2O IceThe Journal of Chemical Physics, 1964
- Proton Magnetic Resonance of Ice Single CrystalJournal of the Physics Society Japan, 1961
- Quadrupole Moment ofPhysical Review B, 1957
- A single-crystal neutron diffraction study of heavy iceActa Crystallographica, 1957