Thallium in organic synthesis. Synthesis of (±)-ocoteine by non-phenolic coupling with thallium tris(trifluoroacetate)(TTFA)

Abstract
(±)-Ocoteine (8), the acetoxy aporphine (9), and 5,7-dihydro-2,3,9,10-tetramethoxydibenzo[c,e]oxepin (5) have been synthesized by direct non-phenolic coupling with thallium tris(trifluoroacetate)(TTFA).

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