Chemical Structure of Fuel-Rich 1,2-C2H4Cl2/CH4/O2/Ar Flames: Effects of Micro-Probe Cooling on the Sampling of Flames of Chlorinated Hydrocarbons
- 1 October 1986
- journal article
- research article
- Published by Taylor & Francis in Combustion Science and Technology
- Vol. 67 (4-6) , 147-157
- https://doi.org/10.1080/00102208908924065
Abstract
The chemical structure of one-dimensional, fuel-rich, laminar flat flames of 1,2-C2 H4Cl2/CH4/ O2/Ar were studied using a quartz micro-probe and on-line mass spectrometry. Mole fraction profiles determined using the same micro-probe with and without cooling water were considerably different, and indicated the continuation of reactions in the uncooled probe. These results suggest the need to evaluate the effects of probe cooling to acquire quantitative data on the structure of flames of chlorinated hydrocarbons.Keywords
This publication has 13 references indexed in Scilit:
- Chemical Structures of Sooting CH3CI/CH4/O2/Ar and CH4/O2/ Ar FlamesCombustion Science and Technology, 1987
- Chemical Species and Temperature Profiles of Laminar Dichloromethane-Methane-Air Flames.I. Variation of Chlorine/ Hydrogen LoadingCombustion Science and Technology, 1987
- Effects of fuel-air equivalence ratio, Temperature, and Inhibitor on the structure of Laminar Methane-air flamesCombustion Science and Technology, 1986
- Chemical Considerations in the Incineration of Chlorinated Methanes I-Methyl ChlorideHazardous Waste, 1984
- Comments on quenching mechanisms in the microprobe sampling of flamesCombustion and Flame, 1983
- Chlorine-catalysed pyrolysis of 1,2-dichloroethane. Part 1.—Experimental results and proposed mechanismJournal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1982
- Further Observations of the Effect of Sample Probes on Pollutant Gases Drawn from Flame ZonesCombustion Science and Technology, 1980
- Modeling and Measurement of Sample Probe Effects on Pollutant Gases Drawn from Flame ZonesCombustion Science and Technology, 1978
- The thermal decomposition of methylene chlorideProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1959
- The Thermal Decomposition of Chloroform. I. Products1aJournal of the American Chemical Society, 1954