Modification of (S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine (BPPFA) as a Ligand for Asymmetric Hydrogenation of Olefins Catalyzed by a Chiral Rhodium(I) Complex
- 1 April 1980
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 53 (4) , 1132-1137
- https://doi.org/10.1246/bcsj.53.1132
Abstract
Asymmetric homogeneous hydrogenation of prochiral olefins catalyzed by chiral rhodium(I) complexes was carried out by using several ferrocenylphosphines as ligands which play a key role of the chiral recognition. Modifications of BPPFA were made in order to examine a steric effect of the given substutient at the asymmetric center on the efficiency of the chiral ligands, indicating the parent BPPFA to be superior to the others examined for the asymmetric hydrogenation of highly functionalized olefins.This publication has 16 references indexed in Scilit:
- 1,2-Bis(diphenylphosphino)-1-phenylethane: a chiral ditertiary phosphine derived from mandelic acid used as a ligand in asymmetric homogeneous hydrogenation catalystsThe Journal of Organic Chemistry, 1979
- Asymmetric synthesis. An asymmetric homogeneous hydrogenation catalyst which breeds its own chiralityJournal of the American Chemical Society, 1978
- Preparation of 1-ferrocenyl-2-methyl-1-propylamine, a highly effective chiral template in asymmetrically induced synthesisTetrahedron, 1978
- Asymmetric synthesis. Production of optically active amino acids by catalytic hydrogenationJournal of the American Chemical Society, 1977
- Asymmetric hydrogenation with new chiral functionalized bisphosphine-rhodium complexesJournal of the American Chemical Society, 1976
- High stereoselectivity in asymmetric Grignard cross-coupling catalyzed by nickel complexes of chiral (aminoalkylferrocenyl)phosphinesJournal of the American Chemical Society, 1976
- Asymmetric hydrogenation with a complex of rhodium and a chiral bisphosphineJournal of the American Chemical Society, 1975
- Stereoselective syntheses. VIII. Retentive nucleophilic displacements of .alpha.-substituted alkylferrocenesThe Journal of Organic Chemistry, 1972
- Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphineJournal of the American Chemical Society, 1972
- Stereoselective syntheses. VI. Correlation of central and planar chirality in ferrocene derivativesJournal of the American Chemical Society, 1970