Adsorption and thermal decomposition of cobalticenium ions on AIPO4-5 studied by X-ray absorption spectroscopy,13C solid-state NMR and FTIR
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 5 (5) , 785-791
- https://doi.org/10.1039/jm9950500785
Abstract
A pentane solution of cobaltocene has been adsorbed on the aluminophosphate molecular sieve AlPO4-5. The product (after exposure to air) contains pentane and water as well as the metallocene in its oxidised form, i.e. cobalticenium. The guest : host material was thermally decomposed at 500 °C in vacuo. XAS, FTIR and 13C NMR show that the thermal decomposition product (ampoules opened in air) contains cobalt atoms bonded to oxygen lattice atoms and possibly some absorbed water.Keywords
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