Structural determination of physisorbed sites for CO2 and Ar gases inside an organometallic framework
- 31 October 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 5 (72) , 411-413
- https://doi.org/10.1039/b312553j
Abstract
The crystal structures of two gas inclusion compounds containing carbon dioxide and argon have been determined by conventional single-crystal X-ray diffraction analysis at room temperature. The analysis revealed different manners of gas inclusion, where hydrogen bond interaction and the π orbital of the conjugate plane cooperatively capture the adsorbed gaseous guests.Keywords
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