Coupling of Allenes and Carbon Dioxide Catalyzed by Electrogenerated Nickel Complexes
- 1 January 1990
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1990 (06) , 361-364
- https://doi.org/10.1055/s-1990-21096
Abstract
Unsaturated carboxylic acids are obtained by reductive electrocarboxylation of a series of allenes with nickel(II) complexes as the catalyst in the presence of a magnesium anode. The influence of steric and electronic effects on the regioselectivity for carbon dioxide incorporation is discussed.Keywords
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