Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex
Top Cited Papers
- 18 October 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2274-2275
- https://doi.org/10.1039/b107881j
Abstract
2-Pyridylmethylimidazolium salts and IrH5(PPh3)2 give an [(N–C)IrH2(PPh3)2]+ species with the imidazole ring bound in the ‘wrong way’: at C-5, not at the expected C-2.Keywords
This publication has 11 references indexed in Scilit:
- A Cationic Iridium Complex Bearing an Imidazol-2-ylidene Ligand as Alkene Hydrogenation CatalystOrganometallics, 2001
- A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalystChemical Communications, 2001
- N-Functionalised heterocyclic carbene complexes of silverJ. Chem. Soc., Dalton Trans., 2000
- Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene LigandsPublished by Wiley ,2000
- Stable CarbenesChemical Reviews, 1999
- Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactionsJournal of Organometallic Chemistry, 1998
- A Facile Synthesis of Unusual Liquid‐Crystalline Gold(I) Dicarbene CompoundsAngewandte Chemie International Edition in English, 1997
- Factors Affecting the Strength of N-H.cntdot..cntdot..cntdot.H-Ir Hydrogen BondsJournal of the American Chemical Society, 1995
- A stable crystalline carbeneJournal of the American Chemical Society, 1991
- Chemie nucleophiler Carbene, XX HX‐Abspaltung aus 1.3‐Diphenyl‐imidazoliumsalzen. Quecksilbersalz‐Carben‐KomplexeEuropean Journal of Inorganic Chemistry, 1970