Fluorodesilylation of alkenyltrimethylsilanes: a new route to fluoroalkenes and difluoromethyl-substituted amides, alcohols or ethers
- 16 January 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 233-234
- https://doi.org/10.1039/b009179k
Abstract
A range of alkenyltrimethylsilanes are converted to alkenyl fluorides by reaction with one equivalent of Selectfluor™ (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)), or difluoromethyl-substituted alcohols, ethers or amides using an excess of Selectfluor™ in the presence of various nucleophiles.Keywords
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