Mechanistische Untersuchungen zur Ligandenfluktuation in den Sandwich-Komplexen [M([12]Krone-4)2]++ / Mechanistic Studies on the Ligand Fluctuations in the Sandwich Complexes [M([12]crown-4)2]++
Open Access
- 1 December 1984
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 39 (12) , 1755-1758
- https://doi.org/10.1515/znb-1984-1223
Abstract
The metal ions Co++ , Ni++ , Mg++ , and Zn++ form the sandwich complexes [M([12]crown-4)2]++ with [12]crown-4 in CD3NO2. From the reaction order of the crown ether exchange a strong outer sphere association between complex and ligand can be inferred. Ligand fluctuation processes occur via an intramolecular associative mechanism from which a very high symmetry of the complexes results.Keywords
This publication has 0 references indexed in Scilit: