Abstract
The preparation of completely clear bromoelpasolites Cs2NaLnBr6 is described. The particular suitability of the resulting products for spectroscopical measurements is demonstrated by the electronic Raman spectrum of Cs2NaPrBr6. Using the crystal field parameter set B4 0 = 232 and B6 0 = 17 cm-1 a good agreement between observed and calculated signals could be achieved.

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