Stereoselective synthesis of β-hydroxy substituted trans-alkenes by the reaction of trans-alkenyltrialkylaluminates with epoxides
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 17-18
- https://doi.org/10.1039/c39760000017
Abstract
Lithium trans-alkenyltrialkylaluminates, prepared by the hydroalumination of alkynes followed by treatment with n-butyl-lithium, react with epoxides to produce β-hydroxy-substituted trans-alkenes, which are readily convertible into βγ-unsaturated carbonyl derivatives.Keywords
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