Optically stable thiosulphinate S-esters: asymmetric synthesis and nucleophilic substitution at sulphinyl sulphur
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 220-221
- https://doi.org/10.1039/c39760000220
Abstract
Optically stable thiosulphinate S-esters containing the t-butylthio-group have been prepared by the asymmetric condensation of sulphinyl chlorides with achiral thiols in the presence of optically active tertiary amines; they have been converted into sulphoxides, sulphinamides, and sulphinates.Keywords
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