Synthesis of (+)-1,3,5,7-tetrakis[2-(1S,3S,5R,6S,8R,10R)-D3-trishomocubanylbuta-1,3-diynyl] adamantane. An optically active organic molecule with T symmetry and of known absolute configuration
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1245-1246
- https://doi.org/10.1039/c39820001245
Abstract
Coupling of 1,3,5,7-tetraethynyladamantane (12) with (+)1-bromo-2-[2-(1S,3S,5R,6S,8R,10R)-D3-trishomocubanyl]ethyne (21) provided the title compound (2) of known absolute configuration whose highest attainable static and time-averaged dynamic symmetry are T and (C3)4 T, respectively.Keywords
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