Preparation, and crystal and molecular structure of π-cyclopentadienyl-η-(tetraphenylborato)ruthenium(II)
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1302-1305
- https://doi.org/10.1039/dt9740001302
Abstract
The preparation of the title compound is reported. Crystals are monoclinic, a= 9·527(4), b= 15·381(6), c= 15·518(7)Å, β= 105·09(5)°, Z= 4, space group P21/c. The structure was determined by Patterson and Fourier methods from diffractometer data and refined by least-squares methods to a final R of 0·032 for 2048 reflections. The ruthenium atom is sandwiched between the cyclopentadienyl ring and one of the phenyl rings of the tetraphenylborate anion. The rings are planar, parallel, and 3·52 Å apart.Keywords
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