Abstract
The new oxide LiAg3O2 was prepared using oxygen pressures of about 300 at. The crystal structure, determined by single crystal X-ray investigations, consists of branched O—Ag—O—Ag chains; Li is coordinated by distorted, edge-sharing oxygen tetrahedra. The space group is Ibam; α = 5.974 Å, b = 9.945 Å, c = 5,694 Å.

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