Investigation of the F+H2 transition state region via photoelectron spectroscopy of the FH−2 anion
- 1 October 1990
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 93 (7) , 5352-5353
- https://doi.org/10.1063/1.459721
Abstract
The photoelectron spectrum of the FH−2 anion is reported. The spectrum provides a probe of the transition state region for the F+H2 reaction. The experimental spectrum is compared to the recent simulation by Zhang and Miller which assumes the T5a potential energy surface for the F+H2 reaction. The experimental spectrum is substantially broader. While this may be due to inaccuracies in the T5a surface, the possibility of additional transitions to low‐lying excited electronic surfaces not included in the simulation must also be considered.Keywords
This publication has 37 references indexed in Scilit:
- Translational basis set contraction in variational reactive scatteringThe Journal of Chemical Physics, 1990
- Threshold photodetachment spectroscopy of the iodine atom + hydrogen iodide transition-state regionThe Journal of Physical Chemistry, 1990
- Quantum reactive scattering in three dimensions using hyperspherical (APH) coordinates. IV. Discrete variable representation (DVR) basis functions and the analysis of accurate results for F+H2The Journal of Chemical Physics, 1990
- Photodissociation and continuum resonance Raman cross sections and general Franck–Condon intensities from S-matrix Kohn scattering calculations with application to the photoelectron spectrum of H2F−+hν→H2+F, HF+H + e−The Journal of Chemical Physics, 1990
- Probing the transition state with negative ion photodetachment: the chlorine atom + hydrogen chloride and bromine atom + hydrogen bromide reactionsThe Journal of Physical Chemistry, 1990
- Kinetic and mechanistic investigations of fluorine atom + water/water-d2 and fluorine atom + hydrogen/deuterium over the temperature range 240-373 KThe Journal of Physical Chemistry, 1989
- Theoretical studies of the potential surface for the F+H2→HF+H reactionThe Journal of Chemical Physics, 1988
- Absolute rate coefficients for F+H2 and F+D2 at T=295–765 K.The Journal of Chemical Physics, 1980
- The temperature dependence of absolute rate constants for the F+H2 and F+D2 reactionsThe Journal of Chemical Physics, 1980
- Energy Distribution Among Reaction Products. VI. F+H2, D2The Journal of Chemical Physics, 1972