Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT studyElectronic supplementary information (ESI) available: experimental; structural data for 1; computational data. See http://www.rsc.org/suppdata/cc/b2/b212453j/

Abstract
The first authenticated example of migration of a methyl group from palladium(II) to a coordinated N-heterocyclic carbene is described.

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