Some factors influencing the absolute intensity of the carbonyl stretching modes of a series of transition-metal pentacarbonylhalide derivatives

1 January 1971

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 3143-3147
https://doi.org/10.1039/j19710003143

Abstract

Available data on the absolute i.r. intensities of carbonyl stretching vibrations of the series of transition-metal pentacarbonylhalides of general formula XM(CO)₅(X = Cl, Br, l; M = Mn, Re) and XM(CO)₅ ^–(X = Cl, Br, l; M = Cr, W) has been analysed. The present treatment recognises that a local carbonyl bond moment derivative need not necessarily be colinear with the carbonyl bond.

Keywords

TRANSITION METAL

This publication has 0 references indexed in Scilit: