Catalytic enantioselective transaminiation of α-keto esters: an organic approach to enzymatic reactions
- 19 September 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2602-2603
- https://doi.org/10.1039/b308395k
Abstract
The half-transamination reaction of α-keto esters with pyridoxamine or 4-picolylamine was found to be catalysed by different metal catalysts in organic solvents giving moderate yields and enantioselectivities of up to 37% ee for methyl-3-indole pyruvate.Keywords
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