Optical rotatory dispersion and circular dichroism. Part LXIX. Camphor derivatives; ‘anti-Octant’ behaviour of hydroxy- and acetoxysubstituents
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- No. 19,p. 2678-2682
- https://doi.org/10.1039/j39700002678
Abstract
C.d. and o.r.d. data are reported for the epimeric 3-hydroxy- and 3-acetoxy-derivatives of (+)-bornan-2-one [(+)-camphor], and the 2-hydroxy- and 2-acetoxy-derivatives of (–)-bornan-3-one [(–)-epi-camphor]. The observed contributions of hydroxy- or acetoxy-groups to amplitudes or Δε values are in the opposite sense to that predicted for alkyl groups by the Octant Rule.Keywords
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